3D4M Ultra Performance

PEKK-A Filament.

A PEKK from the same polymer family as PEEK, made from an amorphous grade whose slow crystallisation gives better Z-layer bonding. Easier to print than PEEK, and inherently flame resistant. read further

  • Better printability than PEEK
  • High temperature resistance
  • Inherently flame resistant (UL94 V-0)
PEKK-A Filament, Natural, 500 g, 1.75 mm
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Color
Diameter
Weight
€265.00
€530.00/kg · excl. VAT
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Freshly produced on demand and typically shipped within 3 working days.

About this material

PEKK-A: the more printable way into the PAEK family.

PEKK-A is a polyetherketoneketone filament, part of the high-performance polyaryletherketone family alongside PEEK. We make it from the PEKK 6000 series, an amorphous grade with a slow crystallisation rate, in its medium-flow version. Chemically it has a high ketone content and a copolymer structure built from terephthalic and isophthalic units.

That chemistry is why it exists. A slow-crystallising grade bonds better between layers in the Z direction, which is where printed parts in this class usually give way first, and it makes the material more printable than PEEK without leaving the performance tier.

It brings high temperature resistance and high chemical resistance, it is light with high tensile strength, and it is inherently flame resistant with a UL 94 V-0 rating at 0.8 mm. Aerospace, energy and transport are its usual sectors, and the material is FAR 25.853 certified.

Easier than PEEK still means demanding. This is a heated-chamber material on an industrial machine, and drying is not optional.

Physical properties
PropertyConditionValueTest method
Density 23 ºC 1.27 g/cm3 ISO 1183
Water Absorption 23 ºC, RH50%, equilibrium 0.44% ISO 62
Water Absorption 23 ºC, RH50%, 24 h, 2 mm 0.07% ISO 62
Water Absorption 23 ºC, immersion, equilibrium 1.07% ISO 62
Water Absorption 23 ºC, immersion, 24 h, 2 mm 0.2% ISO 62
Melt Volume Flow Rate 380 ºC/1 kg 6 cm3/10 min ISO 1133
Mechanical properties
PropertyConditionValueTest method
Tensile modulus 23 ºC, 1 mm/min 2.9 GPa ISO 527-1BA
Tensile Strength Yield point, 23 ºC, 25 mm/min 88 MPa ISO 527-1BA
Elongation at Yield 23 ºC, 25 mm/min 5.4% ISO 527-1BA
Elongation at Break 23 ºC, 25 mm/min > 80% ISO 527-1BA
Tensile Strength Yield point, 125 ºC, 25 mm/min 53 MPa ISO 527-1BA
Elongation at Break 125 ºC, 25 mm/min > 100% ISO 527-1BA
Compression Modulus 23 ºC, 1 mm/min 3.0 GPa ISO 604
Compression Strength 23 ºC, 5 mm/min 108 MPa ISO 604
Flexural Modulus 23 ºC 3.0 GPa ISO 178-93
Flexural Strength Max, 23 ºC 128 MPa ISO 178-93
Unnotched Charpy Impact Strength 23 ºC No Break ISO 179/1eU
Unnotched Charpy Impact Strength -30 ºC No Break ISO 179/1eU
Charpy notched impact strength 23 ºC 5.5 kJ/m2 ISO 179/1eA
Charpy notched impact strength -30 ºC 5.0 kJ/m2 ISO 179/1eA
Thermal properties
PropertyConditionValueTest method
Glass Transition 20 ºC/min 158 ºC DSC
Specific Heat Capacity 23 ºC 1.0 J/(g K)
Heat Deflection Temperature 1.8 MPa 139 ºC ISO 75f
CLTE Average, -100 ºC to Tg 26.5 µm/m/K DMA, tension
Electrical properties
PropertyConditionValueTest method
Electric Strength 100 µm thickness 84 kV/mm IEC 60243-1
Relative Permittivity 23 ºC, 1 MHz 3.0 IEC 60250
Loss Tangent 23 ºC, 1 kHz 0.002 IEC 60250
Volume Resistivity 23 ºC 1.0E+16 ohms•cm ASTM D257
Surface Resistivity 23 ºC 1.0E+16 ohms ASTM D257
Flammability properties
PropertyConditionValueTest method
Flammability Rating 0.8 mm V-0 UL 94
Limiting Oxygen Index 3.2 mm 43% ISO 4589-2
Printer settings & data sheets

Easier than PEEK, which is not the same as easy.

Print at 350 to 400 °C on a bed between 120 and 160 °C, and in a heated chamber between 70 and 150 °C. Use Magigoo HT on a carbon plate, a PEI sheet or glass. There is no open-printer route to this material.

Dry it first.

Bake the filament at 120 °C for six to eight hours before printing. The cost of a dry spool is time, and the cost of a damp one is the part.

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Recommended print settings
ParameterValue
Nozzle temperature350 to 400 °C
Heated bed temperature120 to 160 °C
Print speed20 to 40 mm/s
AdhesionMagigoo HT on carbon plate, PEI sheet or glass
Drying120 °C, 6 to 8 hours
Chamber temperature70 to 150 °C
Empty spool weight
Filament weightSpoolEmpty weight
200 to 750 g RS 200 GH2L PC 243 g
1000 g RS 200 KDL PC 256 g
2000 g RS300/15GHL PC 618 g
Measurements & tolerance

Precision-engineered consistency.

Consistent prints start with a uniform filament shape. We continuously monitor diameter and roundness during production. When filament varies in size or loses its round profile, material flow becomes erratic. This causes under-extrusion and weak layer bonds.

Our manufacturing process keeps the cross-section stable across the full spool. Your printer receives a steady volume of material without pressure drops in the nozzle. You get predictable extrusion on every job, so with PEKK-A you can focus on your design, not your material.

1.75 mm filament
±0.05mm
Diameter tolerance, edge to edge across the spool.
2.85 mm filament
±0.10mm
Diameter tolerance, edge to edge across the spool.
Both diameters
≥95%
Cross-section roundness across the spool.
The production process

Sealed at the source. Never touched by water.*

Unlike manufacturers who cool filament in a water bath, our filament never touches water during production. Moisture inside the material creates bubbles and weakens layer bonding during printing. Water-free production keeps extrusion consistent and bubble-free.

Sealed and ready to print.
We produce on demand. Every spool is vacuum-sealed immediately after extrusion, so it reaches you dry. This process keeps every spool of PEKK-A ready to print out of the box.

* At times of high demand, and for some variants, production may run on a conventional water-cooled line. Contact us before ordering if you require material produced with our water-free process.

Vacuum-sealed filament spool, straight off the extrusion line

Vacuum-sealed on the production line, before it ever leaves the machine.

Traceability & quality assurance

Precision you can track. From pellet to part.

We produce every spool on demand in our own facility. This gives us direct oversight that mass-produced stock lacks. Your spool comes from a fresh, identifiable batch rather than long-term warehouse inventory. We document the production trail for every run.

Documented, not just shipped.
We keep the production logs for every batch we make. On request, we link a Certificate of Analysis and Technical Data Sheet to your specific batch. You get clear data for your spool of PEKK-A.

About 3D4M

Dutch engineering for parts that define the future.

At 3D4M, we develop and manufacture high-performance thermoplastic filaments for demanding applications across aerospace, defence, semiconductor, automotive, medical research, and industrial manufacturing. We work with engineers, researchers, and manufacturers who need materials that go beyond standard specifications.

Our engineering starts with the machines themselves. We design and build our own extrusion lines around our patented extrusion process, combining material expertise with technology developed in-house. For moisture-sensitive polymers, our air-cooling technology offers a water-free cooling option, allowing us to tailor the production process to the material.

Our production facility is built on a single, uncompromising principle: control. From our extrusion technology to precise diameter monitoring and vacuum-sealed packaging, we control every stage to deliver consistent filament with batch traceability.

Trusted by global leaders
Supporting over 100 universities alongside global industry leaders, we have become a trusted partner to advanced research labs and manufacturers worldwide. We bring together material expertise and Dutch engineering to help turn ambitious ideas into reliable, high-performance parts.

3D4M headquarters in Haarlem, the Netherlands

3D4M headquarters, Haarlem, the Netherlands.

Trusted by
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Validating this material for your application?

The leap to a high-performance polymer can be complex. Speak directly with one of our material engineers about your printer setup, target specifications, and material performance. We are here to help you de-risk your validation phase.

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Specify your specs. We'll start your batch.

Experience the benefits of freshly extruded, water-free filament. Select your required diameter and spool weight in the order panel to initiate our on-demand production process. We ship worldwide, vacuum-sealed and ready.

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