3D4M Bio Performance

PLLA Filament.

A biopolymer made entirely from renewable plant sources, industrially compostable to NF EN 13432, and printed on an ordinary desktop machine. We supply it mainly for bioengineering research, where the material itself is part of the experiment. read further

  • Industrially compostable
  • For bioengineering research
  • 100% biobased, non-GMO
PLLA Filament, Natural, 750 g, 1.75 mm
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Color
Diameter
Weight
€75.00
€100.00/kg · excl. VAT
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Freshly produced on demand and typically shipped within 3 working days.

About this material

PLLA: a fully biobased polymer for bioengineering research.

Poly(L-lactic acid) is a biodegradable polyester made entirely from renewable vegetal resources, non-GMO, in line with the NF EN 16785-1 standard for biobased content. It is industrially compostable to NF EN 13432, and production waste can be fed back into production. We sell it in natural only, where its high transparency is part of the point.

It prints in an ordinary PLA window, around 210 °C at the nozzle on a bed between 40 and 60 °C, with no heated chamber. A research group can therefore work with it on the printer it already has, which is unusual for a specialty biopolymer.

It is a stiff material rather than a tough one. Elongation at break stays at or below 5%, so parts are rigid and break rather than bend, and the heat deflection temperature of 55 to 60 °C means a part softens below the temperature of boiling water. This is a material for studying and prototyping, not for parts that carry load or see heat.

We produce the filament in Haarlem with a dry extrusion process and vacuum-seal it at the source, which keeps diameter and roundness constant across the spool.

Physical properties
PropertyConditionValueTest method
Density 1.24 g/cm3 ISO 1183
MFI 190 ºC, 2.16 kg 3 g/10min ISO 1133
Hardness 15 s 81 Shore D ISO 868
Optical properties Transparent
Shrinkage 0.1 to 0.2 %
Mechanical properties
PropertyConditionValueTest method
Tensile strength at break 50 MPa ISO 527
Tensile elongation at break ≤ 5% ISO 527
Young’s Modulus 3500 MPa ISO 527
Flexural Modulus 3350 MPa ISO 178
Charpy impact strength (unnotched) 21 kJ/m2 ISO 179
Thermal properties
PropertyConditionValueTest method
Melt temperature 175 ºC
Heat Deflection Temperature B120 55 to 60 ºC ISO 75-2
Vicat Softening Temperature A50 61 ºC ISO 306
Printer settings & data sheets

An ordinary PLA window, on the printer you already have.

PLLA runs in the same window as plain PLA: around 210 °C at the nozzle, a bed between 40 and 60 °C, and no heated chamber. Print in a room without draft or temperature swings and out of direct sunlight.

Drying.

Dry the filament for three hours at 60 °C before printing, particularly a spool that has been open for a while. Store it sealed, cool, dry and away from light and heat between jobs.

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Recommended print settings
ParameterValue
Nozzle temperature180 to 220 °C (210 °C recommended)
Heated bed temperature40 to 60 °C
Print speed15 to 30 mm/s
AdhesionMagigoo Original on glass or a PEI sheet
Drying60 °C, 3 hours
Moisture contentless than 250 ppm before printing
Empty spool weight
Filament weightSpoolEmpty weight
750 g RS 200 GH2L PS 213 g
Measurements & tolerance

Precision-engineered consistency.

Consistent prints start with a uniform filament shape. We continuously monitor diameter and roundness during production. When filament varies in size or loses its round profile, material flow becomes erratic. This causes under-extrusion and weak layer bonds.

Our manufacturing process keeps the cross-section stable across the full spool. Your printer receives a steady volume of material without pressure drops in the nozzle. You get predictable extrusion on every job, so with PLLA you can focus on your design, not your material.

1.75 mm filament
±0.05mm
Diameter tolerance, edge to edge across the spool.
2.85 mm filament
±0.10mm
Diameter tolerance, edge to edge across the spool.
Both diameters
≥95%
Cross-section roundness across the spool.
The production process

Sealed at the source. Never touched by water.*

Unlike manufacturers who cool filament in a water bath, our filament never touches water during production. Moisture inside the material creates bubbles and weakens layer bonding during printing. Water-free production keeps extrusion consistent and bubble-free.

Sealed and ready to print.
We produce on demand. Every spool is vacuum-sealed immediately after extrusion, so it reaches you dry. This process keeps every spool of PLLA ready to print out of the box.

* At times of high demand, and for some variants, production may run on a conventional water-cooled line. Contact us before ordering if you require material produced with our water-free process.

Vacuum-sealed filament spool, straight off the extrusion line

Vacuum-sealed on the production line, before it ever leaves the machine.

Traceability & quality assurance

Precision you can track. From pellet to part.

We produce every spool on demand in our own facility. This gives us direct oversight that mass-produced stock lacks. Your spool comes from a fresh, identifiable batch rather than long-term warehouse inventory. We document the production trail for every run.

Documented, not just shipped.
We keep the production logs for every batch we make. On request, we link a Certificate of Analysis and Technical Data Sheet to your specific batch. You get clear data for your spool of PLLA.

About 3D4M

Dutch engineering for parts that define the future.

At 3D4M, we develop and manufacture high-performance thermoplastic filaments for demanding applications across aerospace, defence, semiconductor, automotive, medical research, and industrial manufacturing. We work with engineers, researchers, and manufacturers who need materials that go beyond standard specifications.

Our engineering starts with the machines themselves. We design and build our own extrusion lines around our patented extrusion process, combining material expertise with technology developed in-house. For moisture-sensitive polymers, our air-cooling technology offers a water-free cooling option, allowing us to tailor the production process to the material.

Our production facility is built on a single, uncompromising principle: control. From our extrusion technology to precise diameter monitoring and vacuum-sealed packaging, we control every stage to deliver consistent filament with batch traceability.

Trusted by global leaders
Supporting over 100 universities alongside global industry leaders, we have become a trusted partner to advanced research labs and manufacturers worldwide. We bring together material expertise and Dutch engineering to help turn ambitious ideas into reliable, high-performance parts.

3D4M headquarters in Haarlem, the Netherlands

3D4M headquarters, Haarlem, the Netherlands.

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Validating this material for your application?

The leap to a high-performance polymer can be complex. Speak directly with one of our material engineers about your printer setup, target specifications, and material performance. We are here to help you de-risk your validation phase.

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Specify your specs. We'll start your batch.

Experience the benefits of freshly extruded, water-free filament. Select your required diameter and spool weight in the order panel to initiate our on-demand production process. We ship worldwide, vacuum-sealed and ready.

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